Facile Preparation of Unprotected Anomeric Glycosyl Thiols for Glycoconjugate Synthesis
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چکیده
منابع مشابه
Selective anomeric acetylation of unprotected sugars in water.
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A series of glycosyl hemiacetal derivatives have been transformed into thioglycosides and glycosyl thiols in a one-pot two-step reaction sequence mediated by Appel reagent (carbon tetrabromide and triphenylphosphine). 1,2-trans-Thioglycosides and β-glycosyl thiol derivatives were stereoselectively formed by the reaction of the in situ generated glycosyl bromides with thiols and sodium carbonotr...
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ژورنال
عنوان ژورنال: Trends in Glycoscience and Glycotechnology
سال: 2018
ISSN: 0915-7352,1883-2113
DOI: 10.4052/tigg.1722.6j